It is shown that an important role in the phenomenon of amplification of polymer nanocomposites filled with particles of organoclay play interfacial interaction between the polymer filler, determine the conditions of the formation of interfacial regions. Filling in these areas all vnutrigallereynogo space between the plates of layer silicate gives the optimum effect of enhancing the inherent intercalated nanocomposites. Classification nanocomposites according to a particular feature is largely determined by the molecular characteristics of the polymer matrix. Computer simulation method of quantum mechanics strongly supports the results of analytical assessments based on the fractal approach.